\Vul*ca"ni*an\, a. [L. Vulcanius.] 1. Of or pertaining to Vulcan; made by Vulcan; hence, of or pertaining to works in iron or other metals. Ingenious allusions to the Vulcanian panoply which Achilles lent to his feebler friend. --Macaulay. 2. (Geol.) Volcanic.