1. [adj]  subject to appointment
2. [adj]  selected for a job; "the one appointed for guard duty"
3. [adj]  provided with furnishing and accessories (especially of a tasteful kind); "a house that is beautifully appointed"
4. [adj]  fixed or established especially by order or command; "at the time appointed (or the appointed time")

APPOINTED is a 9 letter word that starts with A.